Barbara Bosio

@article{Mazzoccoli2014,
author  = {M. Mazzoccoli, B. Bosio, E. Arato, S. Brandani},
editor  = {Elsevier},
title   = {Comparison of equations-of-state with P–r–T experimental data of binary mixtures rich in CO2 under the conditions of pipeline transport},
url = {http://dx.doi.org/10.1016/j.supflu.2014.09.047 },
year  = {2014},
journal = {Journal of Supercritical Fluids},
volume = {95},
pages = {474-490},
abstract = {Transport of carbon dioxide is an essential feature of Carbon Capture and Storage. Power plants and
industrial production plants – large point sources of CO2 – are often situated far away from storage
locations, thus it is necessary to transport the resulting CO2-rich streams from the point of capture to the
storage/utilization site. The CO2 quality required for transport may influence the choice of the capture
technology and impose limits on the performance requirements.
In order to design CO2 transport networks, it is important to have an accurate knowledge of the thermodynamic
properties of CO2-rich mixtures containing small amounts of impurities. However, a suitable
equation of state under the appropriate conditions for pipeline transport has not been clearly defined yet
and different options may be used for different applications. For a quick evaluation of transport options,
simple cubic EOS may be sufficient, but for accurate measurements of CO2 flows needed for fiscal purposes
more accurate non-analytical EOS may be required.
In this paper the results of different EOS, including both cubic equations and non-analytical equations,
have been compared with P––T experimental data of binary mixtures of carbon dioxide with nitrogen,
oxygen and argon obtained by the authors at the Energy and Environmental Laboratory of Piacenza (LEAP).
Moreover a refitting of the mixture binary interaction parameters has been carried out for analyzed EOS.
The Lee–Kesler–Plöcker, the Perturbated-Chain SAFT equations and the GERG model showed good
prediction of the density of CO2-mixtures in the conditions typical of pipeline transport: “dense” liquid
phase (P above the critical pressure and T below the critical temperature) and CO2 molar concentration
greater than 95%.
Finally, the application of EOS to CO2 transport simulations and pipeline design has been performed in
order to find the best configuration of pipelines on the basis of geometrical characteristics and operating
conditions.},
}

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C. Moliner, B. Bosio, E. Arato, A. Ribes

Comparative study for the energy valorisation of rice straw (article)

Chemical Engineering Transactions, 37, Page(s): 241-246, 2014.

N. Di Giulio, E. Audasso, B. Bosio, J. Han, S.W. Nam, S. McPhail, A. Moreno

The SO2poisoning influence on the kinetics of MCFC (proceedings)

2013.

P. Greppi, B. Bosio, E. Arato

Membranes and molten carbonate fuel cells to capture CO2 and increment energy production in natural gas power plants. (article)

Industrial & Engineering Chemistry Research, 2013.

N. Di Giulio, B. Bosio, V. Cigolotti, S.W. Nam

Experimental and theoretical analysis of H2S effects on MCFCs. (article)

International Journal of Hydrogen Energy, 37, 24, Page(s): 19329–19336, 2012.

D. Bernocco, B. Bosio, E. Arato

Feasibility study of a spouted bed gasification plant. (article)

Chemical Engineering Research and Design, In press, 2012.

M. Mazzoccoli, B. Bosio, E. Arato

Pressure-density-temperature measurements of binary mixtures rich in CO2 for CCS applications. (article)

Journal of Chemical and Engineering Data, 57, Page(s): 2774-2783, 2012.

Mazzoccoli M., Bosio B., Arato E.

Analysis and comparison of Equations-of-State with p-r-T experimental data for CO2 and CO2-mixture pipeline transport (article)

Energy Procedia, 23, Page(s): 274-283, 2012.

B. Bosio, E. Arato, P. Greppi

Technology and Application of Molten Carbonate Fuel Cells. (article)

Fuel Cell Science and Engineering, 1, Page(s): 67-95, 2012.

Puglisi Greta, Rusca Clelia

Elaborazione di dati sperimentali per l'identificazione di parametri cinetici in celle a combustibile a carbonati fusi. (mastersthesis)

2012.

De Battè Matteo

Modello a parametri concentrati di un processo di gassificazione e fusione per il trattamento dei rifiuti (mastersthesis)

2011.

Ferrari Elena

Confronto tra sistemi di assorbimento chimico e celle a carbonati fusi per la cattura della anidride carbonica da esausti di impianti di potenza (mastersthesis)

2010.

Bocciardo Davide - Garbarino Gabriella

Identificazione di parametri cinetici in celle a combustibile a carbonati fusi (mastersthesis)

2010.

Timossi Elena

Applicazione di una unità di separazione con MEA alla cattura della CO2 in esausti da impianti di potenza: preliminare ottimizzazione di progetto e di esercizio tramite simulazione di processo (mastersthesis)

2010.

Greppi P., Bosio B., Arato E.

Feasibility of the integration of a molten carbonate fuel-cell system and an integrated gasiﬁcation combined cycle (article)

International Journal of Hydrogen Energy, 34, Page(s): 8664-8669, 2009.

Marra D., Bosio B., Arato E.

Fluid-Dynamic Characterisation of MCFC Gas Distributors (article)

Chemical Engineering & Processing: Process Intensification, 48, Page(s): 797-807, 2009.

Moricone Erica

Simulazione di impianti a celle a combustibile accoppiati a sistemi tradizionali per la segregazione dell’anidride carbonica (mastersthesis)

2009.

Buzzi Alessandro

Studio per la realizzazione di impainto MCFC da 1 MW alimentato a biomassa (mastersthesis)

2008.

P. Costa, B. Bosio

Identification problems and analysis of the limit current in fuel cells (article)

Journal of Power Sources, 185, 2, Page(s): 1141-1146, 2008.

Greppi P., Bosio B., Arato E.

A steady-State Simulation Tool for MCFC Systems Suitable for On-line Applications (article)

International Journal of Hydrogen Energy, 33, 21, Page(s): 6327-6338, 2008.

B. Bosio, E. Arato, P.Costa

Metodi di identificazione di correnti limite nelle celle a combustibile a carbonati fusi (inproceedings)

Convegno GEIERA2008, Genova, 2008.

C. Lasagna, M. Minetti, B. Bosio

Energy production using biomasses from sewage sludge and agricultural waste (inproceedings)

Second International Symposium on Energy from Biomass and Waste, Venezia, Italy, 2008.

Lusso Roberto

Applicazione innovativa di sistemi celle MCFC per la produzione di energia e idrogeno (mastersthesis)

2008.

Marra Danilo

Fluid-dynamic characterisation of molten carbonate fuel cells in plant optimisation (phdthesis)

2007.

Bogliolo Lorenzo

Valorizzazione energetica di biomassa in un impainto a celle a combustibile (mastersthesis)

2007.

Monteverde Michela

Analisi delle prestazioni di cella a combustibile convenzionali e innovative (mastersthesis)

2007.

D. Marra, B. Bosio

Process analysis of 1 MW MCFC plant (article)

International Journal of Hydrogen Energy, 32, Page(s): 809-818, 2007.

P. Costa, B. Bosio

Diffusive resistance analysis in fuel cells Part 2. Some methods and examples (article)

Journal of Power Sources, 172, Page(s): 346–357, 2007.

P. Costa, B. Bosio

Diffusive resistance analysis in fuel cells Part 1. Some theoretical considerations (article)

Journal of Power Sources, 172, Page(s): 334–345, 2007.

P. Greppi, B. Bosio, E. Arato

Object-oriented modelling applied to hybrid unit operations (inproceedings)

AIDIC, Sauro Pierucci, (Ed.): Chemical Engineering Transactions Vol.11. ICheaP-8, Page(s): 113-118, 2007.

B. Bosio, D. Marra, E. Arato

Analysis on Temperature Distribution on MCFC Cell Plane (inproceedings)

Proc. of Second European Fuel Cell Technology and Applications Conference, Page(s): 123-124, Roma, Italy, 2007.

D. Marra, B. Bosio

Study of a Basic MCFC Unit for Modular Multi MW Systems (inproceedings)

Milano, Ed, AIDIC Servizi S.r.l., (Ed.): ICheaP8 Conference – International Conference on Chemical and Process Engineering, Chem. Eng. Transactions, S. Pierucci, Page(s): 443-448, Ischia, Italy, 2007.

G. Del Buono, B. Bosio

Sewage Sludge Thermochemical Valorisation (inproceedings)

HYSYDays – 2nd World Congress of Young Scientists on Hydrogen, Torino, 2007.

Gregori Simona

Analisi del funzionamento di celle a combustibile a carbonati fusi con Reforming esterno ed interno (mastersthesis)

2006.

Bono Tomaso

Uso di Celle a Combustibile a Carbonati Fusi per l'abbattimento di anidride carbonica (mastersthesis)

2006.

Tomasi, C., Baratieri M., Bosio, B., Arato, E., Baggio, P.

Process analysis of an MCFC power plant fed with a biomass syngas (article)

Journal of Power Sources, 157, 2, Page(s): 765-774, 2006.

P. Costa, A. Ferro, E. Ghiazza, B. Bosio

Seawater deaeration at very low steam flow rates in the stripping section (article)

Desalination, 201, 1-3, Page(s): 306-314, 2006.

P. Greppi, E. Arato, B. Bosio, P. Costa

Process simulation of fuel cell systems: recasting detailed models into system models (inproceedings)

The Fuel Cells Science and Technology, Torino, Italy, 2006.

B. Bosio, E. Arato, P. Greppi, P. Costa

Process simulation of fuel cell systems: identification problems in detailed models (inproceedings)

The Fuel Cells Science and Technology, Torino, Italy, 2006.

E. Peñalvo, D. Alfonso, L.Bogliolo, D. Marra, B. Bosio, A. Pérez-Navarro

Biomass energy valorisation plants based on MCFC for combined heat, power and biofuel production (inproceedings)

World Renewable Energy Congress, Florence, Italy, 2006.

Lusso Roberto

Applicazione innovativa di sistemi a celle MFCF per la produzione di energia e idrogeno (mastersthesis)

2006.

F. Parodi, B. Bosio, E. Arato

Method and system of operating molten carbonate fuel cell (article)

International Patent Application PCT/EP2005/000028, Publication N.WO 2006/072262A1, Page(s): 1-48, 2006.

Poggi Ermanno

Fenomeni chimico-fisici che influenzano le prestazioni delle celle MFCF (mastersthesis)

2005.

Tomasi Christian

Produzione di energia tramite celle a combustibile a partire da biomassa: studio di fattibilità del processo (mastersthesis)

2005.

Rovera Andrea

Lo sfruttamento dei rifiuti solidi urbani dal riciclo alla produzione di energia (mastersthesis)

2005.

Bosio B., Arato E.

Molten Carbonate Fuel Cell system simulation tools (article)

Advances in Fuel Cells 2005, Page(s): 277-290, 2005.

A. Scattolini, B. Bosio

Theoretical and experimental investigation of MCFC performance (inproceedings)

HYSYDays – 1st World Congress of Young Scientists on Hydrogen, Torino, 2005.

D. Marra, B. Bosio

Simulation of Multi-MW MCFC systems (inproceedings)

HYSYDAYS – 1st World Congress of Young Scientists on Hydrogen, Torino, 2005.

P. Costa, A. Ferro, B. Bosio, E.Ghiazza

Seawater deaeration at very low steam flow rates in the stripping section (inproceedings)

Desalination and the Environment, Santa Margherita, Italy, 2005.

B. Bosio, A. Serrafero, E. Arato

Methane steam reforming in MCFC power plants fed with biomass-derived fuels (inproceedings)

Milano, Sauro Pierucci, AIDIC Servizi S.r.l., (Ed.): Chemical Engineering Transactions, Page(s): 719-724, 2005.

M. Pinna, B. Bosio

Fuel cell detailed modelling (inproceedings)

HYSYDays – 1st World Congress of Young Scientists on Hydrogen, Torino, 2005.

C.Tomasi, B. Bosio, E. Arato, P. Baggio

Energetic analysis of an MCFC power plan fed by wood gasification syngas (inproceedings)

Ninth Grove Fuel Cell Symposium, London, UK, 2005.

D. Alfonso, B. Bosio, A. Pérez-Navarro, E. Arato, P. Escribà, J. Valls, L. Sánchez

Advanced fuel cell applications for Mediterranean biomass resources (inproceedings)

World Renewable Energy Congress, Aberdeen, Scotland, UK, 2005.

Trucco Matteo

Simulazione dinamica di celle a combustibile a carbonati fusi tramite modelli dettagliati e semplificati (mastersthesis)

2004.

Mercenaro Omar

Analisi multicriteria di sistemi per la produzione di energia a partire da biomassa nella realtà peruviana (mastersthesis)

2004.

Lusardi M., Bosio B., Arato E.

An example of innovative application in fuel cell system development: CO2 segregation using Molten Carbonate Fuel Cells (article)

Journal of Power Sources, 131, 1-2, Page(s): 351-360, 2004.

Bosio B., Arato E., Costa P., Barbucci A., Cerisola G., Baggio P., Fiori L., Ragazzi M., Viviani M., Parodi F., Capobianco P., Torazza A., Pelizza M. L., Repetto F.

Hydrogen as an energy vector: from production to use in fuel cell systems (inproceedings)

Padova, SGE editore, (Ed.): Atti del 59°Congresso ATI ‘Generazione di Energia e Conservazione dell’Ambiente’, Page(s): 661-672, Genova, 2004.

Coppola C., Bosio B., Arato E.

A clean-up system for syngas fed to MCFC systems (inproceedings)

Milano, Sauro Pierucci, AIDIC Servizi S.r.l., (Ed.): Atti di H2-AGE: When, Where, Why in Chemical Engineering Transactions, Page(s): 277-282, Pisa, 2004.

Dellepiane Daniela

Analisi di processo di impianti elettrogeneratori alimetati con gas derivato da canna da zucchero (mastersthesis)

2003.

Coppola M. Carlotta

Impianti elettrogeneratori alimentati con biomassa gassificata: il problema del "clean-up" (mastersthesis)

2003.

Ferraris Gianni

Reformer a piastre di nuova concezione: sperimentazione su impianto pilota (mastersthesis)

2003.

Dellepiane D., Bosio B., Arato E.

Clean energy from sugarcane waste: feasibility study of an innovative application of bagasse and barbojo (article)

Journal of Power Sources, 122, 1, Page(s): 47-56, 2003.

Bosio B., Arato E., Costa P.

Concentration polarisation in heterogeneous electrochemical reactions: a constistent kinetic evaluation with application to molten carbonate fuel cells (article)

Journal of Power Sources, 115, 2, Page(s): 189-193, 2003.

Barabino L., Dellepiane D., Bosio B., Arato E., Parodi F.

Use of biomass in fuel cell power plant (inproceedings)

Milano, Sauro Pierucci, AIDIC Servizi S.r.l., (Ed.): Atti di Icheap6 in Chemical Engineering Transactions, Page(s): 527-532, Pisa, 2003.

B. Bosio, E. Arato

An example of university role in fuel cell system development (inproceedings)

Eighth Grove Fuel Cell Symposium, Page(s): 4.26, London, 2003.

Imperiale Maria

Stesura di un codice Aspen Modeler® per la simulazione di celle a combustibile (mastersthesis)

2003.

Lusardi Manuela

Utilizzo delle celle a combustibile a carbonati fusi per produrre energia elettrica e concentrare l'anidride carbonica (mastersthesis)

2002.

Barabino Laura

Produzione di energia elettrica mediante celle a combustibile a carbonati fusi alimentate a biomassa (mastersthesis)

2002.

Dodera Stefano

Taratura di un modello di pila a combustibile a carbonati fusi (mastersthesis)

2002.

Dellepiane Daniela

Studio di fattibilità per la produzione di energia elettrica in perù utilizzando celle a combustibile alimentate con biogas da canna da zucchero (mastersthesis)

2002.

E. Ferro, E. Ghiazza, B. Bosio, P. Costa

Modelling of flash and stripping phenomena in deaerators for seawater desalination (article)

Desalination, 142, Page(s): 171-180, 2002.

Bosio B., Costamagna P., Arato E., Costa P.

Modelling approach to fuel cell development (article)

Recent research developments in electrochemistry, 5, Page(s): 21-45, 2002.

A. F. Massardo, B. Bosio

Assessment of Molten Carbonate Fuel Cell Models and Integration with Gas and Steam Cycles (article)

2000 Best Paper Award – Journal of Engineering for Gas Turbines and Power (ASME), 124, Page(s): 103-109, 2002.

Parodi F., Bosio B., Arato E., Costa P.

Molten carbonate fuel cell contribution to CO2 abatement (inproceedings)

Antwerpen, Ed. Technologisch Institut (Ed.): Proc.of Int.Conf.on Future Energy Systems and Technology for CO2 abatement, Page(s): 157-163, Antwerpen, Belgium, 2002.

B. Bosio, E. Arato

Le celle a combustibile a carbonati fusi: sviluppo di applicazioni innovative (inproceedings)

Elettrochimica per il recupero e l’ambiente ERA02, Page(s): 20, Torino, 2002.

E. Arato, B. Bosio

Le celle a combustibile a bassa temperatura: applicazioni per autotrazione e generazione diffusa (inproceedings)

Elettrochimica per il recupero e l’ambiente ERA02, Page(s): 15, Torino, 2002.

Arato E., Bosio B., Costa P., Parodi F.

Preliminary experimental and theoretical analysis of limit performance of molten carbonate fuel cell (article)

Journal of Power Sources, 102, 1-2, Page(s): 74-81, 2001.

Bosio B., Arato E., Parodi F.

Integration of a fuel cell model in a global power plant simulation (Fuel cell power plant process analysis using aspen plus) (inproceedings)

Milano, Jiri Klemes editore, AIDIC Servizi S.r.l., (Ed.): Atti del 4th Conference on process integration, modelling and optimisation for energy saving and pollution reduction PRES01, Page(s): 55-58, Firenze, 2001.

Arato E., Bosio B., Massa R., Parodi F.

Optimisation of the cell shape for industrial MCFC stacks (article)

Journal of Power Sources, 86, 1-2, Page(s): 302-308, 2000.

A. F. Massardo, B. Bosio

Assessment of Molten Carbonate Fuel Cell Models and Integration with Gas and Steam Cycles (inproceedings)

45th ASME International Gas Turbine & Aeroengine Technical Congress – ASME Paper, Monaco, 2000.

Bosio B., Capobianco P., Arato E.

Theoretical model and experimental validation of a pressurized molten carbonate fuel cell (article)

Mass and charge transport in inorganic materials. Fundamentals to devices (Part B), 29, Page(s): 1277-1284, 2000, ISBN: 88-86538-30-8.

Bosio Barbara

Sviluppo di tecnologie di celle a combustibile (phdthesis)

1999.

B. Bosio, P. Costamagna, F. Parodi

Modeling and experimentation of molten carbonate fuel cell reactors in a scale-up process (article)

Chemical Engineering Science, 54, Page(s): 2907-2916, 1999.

T. Alvarez, B. Bosio, F. Parodi, B. Passalacqua, J. Simon, M. Zappaterra

Recent Achievements of MOLCARE Programme: Conditioning and Preliminary Testing of the 100kW MCFC Stack (inproceedings)

3rd International Fuel Cell Seminar, Nagoya Congress Center –Japan, 1999.

Bosio B., Parodi F., Arato E., Costamagna P.

Process analysis of a molten carbonate fuel cell pilot plant (inproceedings)

1999), Ed. AIDIC Servizi S.r.l. (Milano, (Ed.): Atti di The Fourth Italian Conference on chemical and process engineering ICHEAP4, Page(s): 651-654, Firenze, 1999.

F. Parodi, R. Perelli, M. Zappaterra, B. Bosio

Pile a combustibile a carbonati fusi: principali esperienze e risultati in Ansaldo ricerche (inproceedings)

“Pile a combustibile: tecnologie e materiali” – Associazione Italiana di Metallurgia, Milano, 1999.

F. Parodi, A. Torazza, B. Bosio

Misure e Metodi Sperimentali nelle Pile a Combustibile a Carbonati Fusi (inproceedings)

(Padova), SGE – Servizi Grafici Editoriali (Ed.): Mis – Mac VI – Metodi di Sperimentazione nelle Macchine, Page(s): 263 273, Genova, 1999.

E. Arato, B. Bosio, R. Massa, F. Parodi

From square to rectangular cells in a MCFC scale-up process: experimental and simulation results optimising operating conditions (inproceedings)

Sixth Grove Fuel Cell Symposium, Page(s): 46, London, 1999.

B. Bosio, P. Costamagna, F. Parodi, B. Passalacqua

Industrial experience on the development of the molten carbonate fuel cell technology (article)

Journal of Power Sources, 74, Page(s): 175-187, 1998.

F. Parodi, B. Bosio, P. Costamagna

The Effects of Fuel Choice on MCFC Stack Operation Using High Temperature Gas Recycling (inproceedings)

Fuel Cell Seminar 1998: Fuel Cells- Clean Energy for Today’s World, Page(s): 178 – 181, Palm Springs, California (USA), 1998.

Bosio B., Arato E., Costamagna P., Parodi F.

Sviluppo di tecnologie di celle a combustibile (inproceedings)

Eris, Ed. AIDIC, Milano e ed. (Ed.): Atti del Congresso GRICU 1998 e ICP, Page(s): 119-122 e 252-255, Ferrara, 1998.

B. Bosio, P. Costamagna, F. Parodi

Modeling and Experimentation of Molten Carbonate Fuel Cell Reactors in a Scale-Up Process (inproceedings)

15th International Symposium on Chemical Reaction Engineering, Page(s): 103-104, Newport Beach, California (USA), 1998.

C. Lasagna, M. Minetti, B. Bosio

Energy production using biomasses from sewage sludge and agricultural waste (article)

Waste Management, 0000.

L. Fiori, G. Crosariol, B. Bosio

Exploitation of exhausted grape pomace: by-product separation and energy generation (article)

Biomass and Bioenergy, 0000.

Arni S., Bosio B., Arato E.

Syngas from sugarcane pyrolysis: an experimental study for fuel cell application (article)

Renewable Energy, 0000.

M. Baratieri, P. Baggio, B. Bosio, M. Grigiante

The use of biomass syngas in IC engines and CCGT plants: a comparative analysis (article)

Applied Thermal Engineering, 0000.

Rotondi Marco C.

Gassificazione autotermica di fanghi e diverse biomasse (mastersthesis)

0000.